Handling Chemicals Safely
General Principles
Basic Laboratory Rules
Handling Chemicals Safely
Handling Glassware Safely
Hazard Warning Signs
Personal Protection
Harmful and Toxic Chemicals

The difference between a harmful chemical and a toxic one is a matter of degree; chemicals which are particularly harmful being classified as toxic. Harmful and toxic chemicals must laways be handled in a fume cupboard with the glass front pulled down as far as is practicable to ensure that a good air-flow. It is also essential to wear protective gloves and take particular note of any special instructions about disposal and what to do in case of spillage.

Examples of harmful and toxic materials are aniline, bromine, chlorofrorm, methanol and cyanide salts

Flammable Chemicals

Many solvents and reagents used in the laboratory are highly flammable and so there should never be naked flames in placies where they are being used. The heating of flammable materials should be carried out using water baths, heating mantles or hot plates.

Examples of highly flammable solvents are diethyl ether, petroleum ether, toluene, acetone (propanone) and ethyl acetate (ethy ethanoate).

Corrosive Chemicals

The most commonly encountered corrosive materials are acids and alkalis although many other types of chemical fall into this category. It is essential to wear appropriate protective gloves when handling corrosive material and if there is contact with the skin it should be washed off immediately with plenty of water. It may also be necessary to seek medical attention.

Examples of corrosive materials are the mineral acids (hydrochloric, nitric, sulphuric and phoshoric acids), strong alkalis such as sodium hydroxide and potassium hydroxide.

Oxidising Agents

Oxidising agents are dangerous because they can cause fires if they make contact with any combustable material, particularly if they are disposed of carelessly.

Examples of oxidising agents are potassium dichromate (VI), potassium manganate (VII), concentrated nitric acid as well as hydrogen peroxide.

Explosive Reagents

Many substances are explosion hazards because of their extreme reactivity with water. Other compounds are explosive because they are unstable, particularly if heated or when dry. When handling such chemicals it is essential to use only small amounts and protect yourself with a face mask and a safety screen.

Examples of explosion hazards are the alkali metals sodium and potassium.

Irritants

Chemicals which can irritate the eyes and or the skin should always be handled in fume cupboards.

Examples of irritants are acid chlorides, thionyl chloride as well as certain chloro compounds.